METAL-METAL INTERACTIONS IN COMPLEXES WIT H A DOUBLE DIMETHYLSILANDIYL-BRIDGED DICYCLOPENTADIENYL LIGAND

Authors
SIEMELING U JUTZI P BILL E TRAUTWEIN AX
Citation
U. Siemeling et al., METAL-METAL INTERACTIONS IN COMPLEXES WIT H A DOUBLE DIMETHYLSILANDIYL-BRIDGED DICYCLOPENTADIENYL LIGAND, Journal of organometallic chemistry, 463(1-2), 1993, pp. 151-154
Citations number
33
Categorie Soggetti
Chemistry Inorganic & Nuclear","Chemistry Inorganic & Nuclear
Journal title
Journal of organometallic chemistry → ACNP
ISSN journal
0022328X
Volume
463
Issue
1-2
Year of publication
1993
Pages
151 - 154
Database
ISI
SICI code
0022-328X(1993)463:1-2<151:MIICWH>2.0.ZU;2-G
Abstract
The metal-metal interaction in the mixed-valence ferrocenium salt [tra ns-CpFeLFeCp*]+PF6- ([5(+)]PF6-) (Cp* = C(5)Me(5), L = [C(5)H(3)SiMe( 2)](2)) was investigated by cyclic voltammetry, electron spectroscopy, EPR and temperature dependent Mossbauer spectroscopy. The compound is best described as a valence-localised system (class I according to Ro bin and Day).