Authors
Citation
B. Korybutdaszkiewicz, METAL-ION PROMOTED NUCLEOPHILIC-SUBSTITUTION OF HYDROGEN IN CHELATED MACROCYCLIC ALPHA-DI-IMINE, Journal of coordination chemistry, 27(1-3), 1992, pp. 219-221
Citations number
8
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
ISSN journal
00958972
Volume
27
Issue
1-3
Year of publication
1992
Part
B
Pages
219 - 221
Database
ISI
SICI code
0095-8972(1992)27:1-3<219:MPNOHI>2.0.ZU;2-L
Abstract
Base-catalyzed addition of nitromethane to the Ni(II) co-ordinated alp
ha-di-imine, followed by elimination of HNO2 and rearrangement of the
double bond formed, leads to the methyl substituted product, i.e. the
nucleophilic substitution of the imine hydrogens occurred.