W. Wang et al., PREPARATION OF SUBMICRON SPHERICAL-PARTICLES OF SILICA BY THE WATER-IN-OIL MICROEMULSION METHOD, Colloids and surfaces. A, Physicochemical and engineering aspects, 81, 1993, pp. 177-180
Submicron spherical particles of colloidal silica were prepared by the
hydrolysis of sodium silicate in a Triton X-100-hexanol-cyclohexane-w
ater microemulsion system. The average diameter of the silica particle
s obtained was about 30 nm. The formation of a microemulsion by using
a cyclohexane solution of Triton X-100 was described. The effects of t
emperature and the concentration of the aqueous Na2SiO3 solution on th
e solubilization were investigated and the results showed that the sol
ubilization decreased with increasing concentration of Na2SiO3 and tha
t an optimum temperature existed for the system.