CONCERNING THE DIASTEREOFACIAL SELECTIVITY OF ALDOL REACTIONS OF CHIRAL METHYL KETONE ENOLATES - EVIDENCE FOR REMOTE CHELATION IN THE BAFILOMYCIN ALDOL REACTION

Authors
ROUSH WR BANNISTER TD WENDT MD
Citation
Wr. Roush et al., CONCERNING THE DIASTEREOFACIAL SELECTIVITY OF ALDOL REACTIONS OF CHIRAL METHYL KETONE ENOLATES - EVIDENCE FOR REMOTE CHELATION IN THE BAFILOMYCIN ALDOL REACTION, Tetrahedron letters, 34(52), 1993, pp. 8387-8390
Citations number
36
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Tetrahedron letters → ACNP
ISSN journal
00404039
Volume
34
Issue
52
Year of publication
1993
Pages
8387 - 8390
Database
ISI
SICI code
0040-4039(1993)34:52<8387:CTDSOA>2.0.ZU;2-L
Abstract
Evidence is presented that the aldol reactions of the lithium enolates of 4 and 7 proceed preferentially by way of chelated transition struc ture 19.