CATALYTIC ENANTIOSELECTIVE DIELS-ALDER REACTIONS USING TITANIUM COMPLEXES OF CIS-N-SULFONYL-2-AMINO-1-INDANOLS

Citation
Ej. Corey et al., CATALYTIC ENANTIOSELECTIVE DIELS-ALDER REACTIONS USING TITANIUM COMPLEXES OF CIS-N-SULFONYL-2-AMINO-1-INDANOLS, Tetrahedron letters, 34(52), 1993, pp. 8399-8402
Citations number
11
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
ISSN journal
00404039
Volume
34
Issue
52
Year of publication
1993
Pages
8399 - 8402
Database
ISI
SICI code
0040-4039(1993)34:52<8399:CEDRUT>2.0.ZU;2-1
Abstract
A titanium complex derived from (1R, (2,4,6-trimethylbenzenesulfonyl)- 2-amino-1-indanol catalyzes the Diels-Alder reaction of 2-bromoacrolei n and cyclopentadiene with 96.5:3.5 enantioselectivity. A new and effi cient synthesis of 2-amino-1-indanol (6) contributes to the potential of this methodology.