SYNTHETIC STUDIES ON OLIGOMYCINS - ENANTIOSPECIFIC SYNTHESIS OF THE OLIGOMYCIN-B SPIROKETAL PORTION AND ESTABLISHMENT OF THE ABSOLUTE STEREOCHEMISTRY OF OLIGOMYCIN-B

Authors
NAKATA M ISHIYAMA T HIROSE Y MARUOKA H TATSUTA K
Citation
M. Nakata et al., SYNTHETIC STUDIES ON OLIGOMYCINS - ENANTIOSPECIFIC SYNTHESIS OF THE OLIGOMYCIN-B SPIROKETAL PORTION AND ESTABLISHMENT OF THE ABSOLUTE STEREOCHEMISTRY OF OLIGOMYCIN-B, Tetrahedron letters, 34(52), 1993, pp. 8439-8442
Citations number
24
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Tetrahedron letters → ACNP
ISSN journal
00404039
Volume
34
Issue
52
Year of publication
1993
Pages
8439 - 8442
Database
ISI
SICI code
0040-4039(1993)34:52<8439:SSOO-E>2.0.ZU;2-Y
Abstract
The enantiospecific synthesis of the oligomycin B degradation product 2, corresponding to the C19-C34 spiroketal portion, has been achieved by sequential coupling of the C19-C21, C22-C27, and C28-C34 subunits, establishing the absolute stereochemistry of oligomycin B.