TOTAL SYNTHESES OF BOTH ENANTIOMERS OF SARCOPHYTOL-A AND SARCOPHYTOL-T BASED ON STEREOSPECIFIC [2,3]WITTIG REARRANGEMENT

Authors
KODAMA M YOSHIO S YAMAGUCHI S FUKUYAMA Y TAKAYANAGI H MORINAKA Y USUI S FUKAZAWA Y
Citation
M. Kodama et al., TOTAL SYNTHESES OF BOTH ENANTIOMERS OF SARCOPHYTOL-A AND SARCOPHYTOL-T BASED ON STEREOSPECIFIC [2,3]WITTIG REARRANGEMENT, Tetrahedron letters, 34(52), 1993, pp. 8453-8456
Citations number
17
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Tetrahedron letters → ACNP
ISSN journal
00404039
Volume
34
Issue
52
Year of publication
1993
Pages
8453 - 8456
Database
ISI
SICI code
0040-4039(1993)34:52<8453:TSOBEO>2.0.ZU;2-R
Abstract
Both enantiomers of sarcophytols A (1) and T (2), cembranolide diterpe nes isolated from a soft coral, were synthesized from a common chiral intermediate, obtained by baker's yeast reduction, using a stereospeci fic [2,3]Wittig rearrangement as the key step.