TANDEM PHOTOCHEMICAL OR THERMAL [1,5]-H, THERMAL [1,5]-SI MIGRATIONS OF VINYL SILANES

Authors
Citation
Mc. Pirrung et Yr. Lee, TANDEM PHOTOCHEMICAL OR THERMAL [1,5]-H, THERMAL [1,5]-SI MIGRATIONS OF VINYL SILANES, Tetrahedron letters, 34(51), 1993, pp. 8217-8220
Citations number
11
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
ISSN journal
00404039
Volume
34
Issue
51
Year of publication
1993
Pages
8217 - 8220
Database
ISI
SICI code
0040-4039(1993)34:51<8217:TPOT[T>2.0.ZU;2-V
Abstract
The irradiation or thermolysis of o-hydroxystyryl vinylsilanes results in migration of the silyl group to the phenolic oxygen via consecutiv e [1,5]-H and [1,5]-Si shifts.