ASYMMETRIC DIHYDROXYLATION OF TERTIARY ALLYLIC ALCOHOLS

Authors
WANG ZM SHARPLESS KB
Citation
Zm. Wang et Kb. Sharpless, ASYMMETRIC DIHYDROXYLATION OF TERTIARY ALLYLIC ALCOHOLS, Tetrahedron letters, 34(51), 1993, pp. 8225-8228
Citations number
3
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Tetrahedron letters → ACNP
ISSN journal
00404039
Volume
34
Issue
51
Year of publication
1993
Pages
8225 - 8228
Database
ISI
SICI code
0040-4039(1993)34:51<8225:ADOTAA>2.0.ZU;2-L
Abstract
The asymmetric dihydroxylation (AD) of tertiary allylic alcohols is ex amined. Goad to excellent ee's are obtained with trans-di- and tri-sub stituted tertiary allylic alcohols of different substitution patterns except for a trisubstituted case where the tertiary carbinol substitue nt is on the disubstituted olefinic carbon.