NEOCLERODANE DITERPENOIDS FROM SCUTELLARIA-ALPINA SUBSP JAVALAMBRENSIS

Authors
DELATORRE MC RODRIGUEZ B BRUNO M MALAKOV PY PAPANOV GY PIOZZI F SAVONA G
Citation
Mc. Delatorre et al., NEOCLERODANE DITERPENOIDS FROM SCUTELLARIA-ALPINA SUBSP JAVALAMBRENSIS, Phytochemistry, 34(6), 1993, pp. 1589-1594
Citations number
22
Categorie Soggetti
Plant Sciences
Journal title
Phytochemistry → ACNP
ISSN journal
00319422
Volume
34
Issue
6
Year of publication
1993
Pages
1589 - 1594
Database
ISI
SICI code
0031-9422(1993)34:6<1589:NDFSSJ>2.0.ZU;2-W
Abstract
Three new neo-clerodane derivatives, scutalpins B-D, were isolated fro m the acetone extract of the aerial parts of Scutellaria alpina subsp. javalambrensis. The structures of these compounds were established ma inly by spectroscopic means as (11S)-11,19-diacetoxy-4 alpha,18-epoxy- 8 beta-hydroxy-6 alpha-tigloyloxy-13-neo-cleroden-15,16-olide (scutalp in B), (11S)-19-acetoxy-4 alpha,18-epoxy-8 beta,11-dihydroxy-6 alpha-t igloyloxy-13-neo-cleroden-15,16-olide (scutalpin C) and (13S)-11 beta, 19-diacetoxy-4 alpha,18;8 beta,13-diepoxy-6 alpha-tigloyloxy-neo-clero dan-15,16-olide (scutalpin D).