The oxygen-induced breakup of vicinal Ag(110) surfaces into (110) face
ts and step bunches is measured with scanning tunneling microscopy. Fa
ceting transitions are recorded in real time at room temperature for t
wo surface orientations. A vicinal Ag(110) surface misoriented by 2-de
grees towards [001] facets via the growth of isolated nuclei. Step-pos
ition fluctuations of increasing magnitude are observed prior to facet
ing, revealing a critical terrace width of approximately 100 angstrom.
In contrast, oxygen exposure causes Ag(110) misoriented by 2-degrees
towards [331BAR] to facet spontaneously with no evident nucleation bar
rier.