STANDARDIZATION OF NEAR-INFRARED SPECTRA IN THE WAVELET DOMAIN

Citation
B. Walczak et al., STANDARDIZATION OF NEAR-INFRARED SPECTRA IN THE WAVELET DOMAIN, Chemometrics and intelligent laboratory systems, 36(1), 1997, pp. 41-51
Citations number
32
Categorie Soggetti
Computer Application, Chemistry & Engineering","Instument & Instrumentation","Chemistry Analytical","Computer Science Artificial Intelligence","Robotics & Automatic Control
ISSN journal
01697439
Volume
36
Issue
1
Year of publication
1997
Pages
41 - 51
Database
ISI
SICI code
0169-7439(1997)36:1<41:SONSIT>2.0.ZU;2-Z
Abstract
A new standardization method based on transferring near-infrared (NIR) spectra in the wavelet domain is proposed. For each NIR spectrum, wav elet transform coefficients are computed, and the transfer step is per formed by relating the wavelet transform coefficients of spectra obtai ned on both instruments with univariate linear models. This method is applied to two different data sets, and its performance is compared wi th the piecewise direct standardization method. The results obtained w ith this new method are better than those obtained by PDS, the biggest improvement occurring when very few standardization samples were used to estimate the standardization parameters. Both PDS and wavelet appr oaches offer advantages only when the spectral differences are local. When spectral differences are global, other methods such as the slope/ bias correction function as well.