THE MECHANISM OF CHAIN TERMINATION IN THE REACTION OF LOW-TEMPERATURELIQUID-PHASE OXIDATION OF HEXAFLUOROPROPYLENE AT LOW-OXYGEN PRESSURES

Authors
SHAPOVALOV VV POLUEKTOV VA
Citation
Vv. Shapovalov et Va. Poluektov, THE MECHANISM OF CHAIN TERMINATION IN THE REACTION OF LOW-TEMPERATURELIQUID-PHASE OXIDATION OF HEXAFLUOROPROPYLENE AT LOW-OXYGEN PRESSURES, Kinetics and catalysis, 34(3), 1993, pp. 380-382
Citations number
14
Categorie Soggetti
Chemistry Physical
Journal title
Kinetics and catalysis → ACNP
ISSN journal
00231584
Volume
34
Issue
3
Year of publication
1993
Pages
380 - 382
Database
ISI
SICI code
0023-1584(1993)34:3<380:TMOCTI>2.0.ZU;2-O
Abstract
The effects of both the oxygen pressure ranging from 1.47 x 10(5) to 1 9.6 x 10(5) Pa at 303 K and from 0.98 x 10(5) to 19.6 x 10(5) Pa at 27 3 K and the late of initiation of primary reaction centers at low oxyg en pressures on the rates of hexafluoropropylene consumption and produ ct formation were investigated. Chain termination was shown to proceed via the 2RO(.) --> ROOR reaction.