ANODIC POTENTIAL HOMO ENERGY RELATIONS OF FLUORENE DERIVATIVES

Authors
SEN S CELEBI N TURKER L ONAL AM
Citation
S. Sen et al., ANODIC POTENTIAL HOMO ENERGY RELATIONS OF FLUORENE DERIVATIVES, Bulletin des Societes chimiques belges, 102(9), 1993, pp. 583-587
Citations number
7
Categorie Soggetti
Chemistry
Journal title
Bulletin des Societes chimiques belges → ACNP
ISSN journal
00379646
Volume
102
Issue
9
Year of publication
1993
Pages
583 - 587
Database
ISI
SICI code
0037-9646(1993)102:9<583:APHERO>2.0.ZU;2-6
Abstract
Anodic oxidation peak potentials (E(p,a)) of some fluorene derivatives were measured on a Pt-degrees electrode versus Ag-degrees/Ag+ in acet onitrile-TBAFB by cyclic voltammetry. The highest occupied molecular o rbital (HOMO) energies of the compounds were calculated within the Huc kel molecular orbital (HMO) framework. The measured E(p,a) values were correlated to theoretical HOMO energies with a linear regression mode l.