This naive supposition that the central vertex(es) in polycyclic graph
s should always belong to central ring(s) was examined for various cas
es of systems containing condensed (fused) 3-, 4-, 5-, 6- and 7-member
ed rings, as well as combinations of 5- and 7-membered rings. It was f
ound that this conjecture is a general trend valid in the great majori
ty of cases. However, counterexamples with the smallest number of ring
s are reported for all types of these systems.