A GEOMETRICAL APPROACH TO THE DEGREE OF CHIRALITY AND ASYMMETRY

Authors
Citation
Z. Zimpel, A GEOMETRICAL APPROACH TO THE DEGREE OF CHIRALITY AND ASYMMETRY, Journal of mathematical chemistry, 14(3-4), 1993, pp. 451-465
Citations number
34
Categorie Soggetti
Chemistry,Mathematics
ISSN journal
02599791
Volume
14
Issue
3-4
Year of publication
1993
Pages
451 - 465
Database
ISI
SICI code
0259-9791(1993)14:3-4<451:AGATTD>2.0.ZU;2-Z
Abstract
A new measure of the degree of chirality and asymmetry of a finite num ber of particles is proposed. To this end a space of configurations of identical particles is defined as the orbit space of the group of all permutations of particles embedded in an Euclidean space. This space is shown to be a metric space and the action of the translation and or thogonal groups is also defined. The results are applied to the study of an algebra of polynomials on the configuration space and its equiva lence to the algebra of symmetric Cartesian tensors is demonstrated. A n illustrative example is presented. Some general features of chiralit y are also briefly discussed.