ZINC PROMOTED ADDITION OF METHYL 2,2-DIHALOCARBOXYLATES TO CARBONYL-COMPOUNDS

Authors
BENINCASA M FORTI L GHELFI F LIBERTINI E PAGNONI UM
Citation
M. Benincasa et al., ZINC PROMOTED ADDITION OF METHYL 2,2-DIHALOCARBOXYLATES TO CARBONYL-COMPOUNDS, Synthetic communications, 26(22), 1996, pp. 4113-4122
Citations number
63
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Synthetic communications → ACNP
ISSN journal
00397911
Volume
26
Issue
22
Year of publication
1996
Pages
4113 - 4122
Database
ISI
SICI code
0039-7911(1996)26:22<4113:ZPAOM2>2.0.ZU;2-I
Abstract
Methyl 2,2-dihalocarboxylates add easily to carbonyl compounds in fair to good yields through the intermediate formation of 2-haloester enol ates; the reaction is promoted by zinc, following a ''Barbier'' type p rocedure.