The diffusion barrier for Pd/Pd(100) is determined via LEED experiment
s independently from: (i) the onset of temperature variation of the Br
agg intensity in both deposition and annealing experiments; and (ii) c
omparison of experimental and model values for the ring diameter of th
e diffuse diffraction profile at a single higher temperature in the nu
cleation-and-growth regime. A value of 12-14 kcal/mol is consistently
obtained.