Because the charging of polyaniline films occurs in the bulk of the ma
terial rather than exclusively at the polymer-electrolyte interface, t
he use of thick polymer films for battery applications is justifiable.
Here, we present a method for producing soluble polyaniline which can
be cast to form free-standing films. Investigation by scanning electr
on microsopy (SEM) has shown that these films are significantly more c
ompact than those made by standard electropolymerization.