THE EXOTIC POTENTIAL CURVE OF THE 3(1)PI(G) STATE OF K-2 BY OPTICAL-OPTICAL DOUBLE-RESONANCE SPECTROSCOPY

Authors
KIM JT WANG H BAHNS JT STWALLEY WC
Citation
Jt. Kim et al., THE EXOTIC POTENTIAL CURVE OF THE 3(1)PI(G) STATE OF K-2 BY OPTICAL-OPTICAL DOUBLE-RESONANCE SPECTROSCOPY, Journal of molecular spectroscopy, 181(2), 1997, pp. 389-393
Citations number
12
Categorie Soggetti
Spectroscopy,"Physics, Atomic, Molecular & Chemical
Journal title
Journal of molecular spectroscopy → ACNP
ISSN journal
00222852
Volume
181
Issue
2
Year of publication
1997
Pages
389 - 393
Database
ISI
SICI code
0022-2852(1997)181:2<389:TEPCOT>2.0.ZU;2-2
Abstract
The Rydberg-Klein-Rees potential curve of the 3(1) Pi(g), state which covers the internuclear distance from 3.59926 to 6.76571 Angstrom is c onstructed from the experimentally determined B-nu and G(nu) values. T he predicted exotic shape (change in slope outside similar to 5.7 Angs trom) agrees with the experimental results. The dissociation energy of this state which dissociates to the K(4s) + K(5p) atomic asymptotic l imit is determined to be 2731.292 +/- 0.085 cm(-1). (C) 1997 Academic Press.