TRIPHENYLARSINE OXIDE AS AN EXTRACTANT FOR TITANIUM(IV), ZIRCONIUM(IV) AND HAFNIUM(IV)

Citation
Ng. Bhilare et al., TRIPHENYLARSINE OXIDE AS AN EXTRACTANT FOR TITANIUM(IV), ZIRCONIUM(IV) AND HAFNIUM(IV), Analytical letters, 30(1), 1997, pp. 173-185
Citations number
15
Categorie Soggetti
Chemistry Analytical
Journal title
ISSN journal
00032719
Volume
30
Issue
1
Year of publication
1997
Pages
173 - 185
Database
ISI
SICI code
0003-2719(1997)30:1<173:TOAAEF>2.0.ZU;2-Y
Abstract
A systematic study on the solvent extraction behaviour of quadrivalent titanium, zirconium and hafnium from salicylate media using triphenyl arsine oxide as an extractant has been undertaken and reported in this manuscript. The optimum extraction conditions are evaluated from crit ical study of various experimental parameters. The probable compositio n of the extracted species is ascertained from logD-logC plots. The me thod is rapid, accurate and highly reproducible.