EXPERIMENTAL-STUDY OF ELEMENTARY REACTIONS OF FO RADICALS .6. REACTION WITH NO2

Authors
BEDZHANYAN YR MARKIN EM GERSHENZON YM
Citation
Yr. Bedzhanyan et al., EXPERIMENTAL-STUDY OF ELEMENTARY REACTIONS OF FO RADICALS .6. REACTION WITH NO2, Kinetics and catalysis, 34(2), 1993, pp. 190-193
Citations number
29
Categorie Soggetti
Chemistry Physical
Journal title
Kinetics and catalysis → ACNP
ISSN journal
00231584
Volume
34
Issue
2
Year of publication
1993
Pages
190 - 193
Database
ISI
SICI code
0023-1584(1993)34:2<190:EOEROF>2.0.ZU;2-C
Abstract
The reactions FO + NO2 --> F + NO3, (a) FO + NO2 --> reaction products (other than F), (b) FO + NO2 --> M FONO2 + M, (c) were studied by com bined EPR/IR LMR spectrometry in a flow system at p = (2 - 47) torr an d T = 300 - 500 K. The rate constants and their associated uncertainti es are as follows: k(a) = (9.9 +/- 0.6) x 10(-13) (T/300)0.47 +/- 0.19 cm3/s at 300 - 500 K, k(b) = (1.4 +/- 0.1) x 10(-13) CM3/s at 300 K, k(c) = (5.3 +/- 0.6) x 10(-32) cm6/s at 300 K.