STUDIES ON THE CONSTITUENTS OF CALLIANDRA-ANOMALA (KUNTH) MACBR .1. STRUCTURE ELUCIDATION OF 2 ACYLATED TRITERPENOIDAL SAPONINS

Citation
T. Takeda et al., STUDIES ON THE CONSTITUENTS OF CALLIANDRA-ANOMALA (KUNTH) MACBR .1. STRUCTURE ELUCIDATION OF 2 ACYLATED TRITERPENOIDAL SAPONINS, Chemical and Pharmaceutical Bulletin, 41(12), 1993, pp. 2132-2137
Citations number
15
Categorie Soggetti
Pharmacology & Pharmacy",Chemistry
ISSN journal
00092363
Volume
41
Issue
12
Year of publication
1993
Pages
2132 - 2137
Database
ISI
SICI code
0009-2363(1993)41:12<2132:SOTCOC>2.0.ZU;2-U
Abstract
Two novel triterpenoidal saponins, called calliandra saponins A and E, were isolated from the branches of Calliandra anomala[a (KUNTH) MACBR . On the basis of the chemical and physicochemical evidence, their str uctures were defined as -(1-->6)-2-acetamido-2-deoxy-beta-D-glucopyran osyl echinocystic acid yl-2,7-octadienoyl-(1-->6)]-beta-D-glucopyranos yl} ester (4) and -(1-->6)-2-acetamido-2-deoxy-beta-D-glucopyranosyl e chinocystic acid -xylopyranosyl-(1-->4)]-alpha-L-rhamnopyranosyl-(1 -2 ',7'-octadienoyl-(1-->6)]-beta-D-glucopyranosyl} ester (5), respective ly.