T. Takeda et al., STUDIES ON THE CONSTITUENTS OF CALLIANDRA-ANOMALA (KUNTH) MACBR .1. STRUCTURE ELUCIDATION OF 2 ACYLATED TRITERPENOIDAL SAPONINS, Chemical and Pharmaceutical Bulletin, 41(12), 1993, pp. 2132-2137
Two novel triterpenoidal saponins, called calliandra saponins A and E,
were isolated from the branches of Calliandra anomala[a (KUNTH) MACBR
. On the basis of the chemical and physicochemical evidence, their str
uctures were defined as -(1-->6)-2-acetamido-2-deoxy-beta-D-glucopyran
osyl echinocystic acid yl-2,7-octadienoyl-(1-->6)]-beta-D-glucopyranos
yl} ester (4) and -(1-->6)-2-acetamido-2-deoxy-beta-D-glucopyranosyl e
chinocystic acid -xylopyranosyl-(1-->4)]-alpha-L-rhamnopyranosyl-(1 -2
',7'-octadienoyl-(1-->6)]-beta-D-glucopyranosyl} ester (5), respective
ly.