ELECTRODIALYSIS IN A NONAQUEOUS MEDIUM - A CLEAN PROCESS FOR THE PRODUCTION OF ACETOACETIC ESTER

Citation
S. Sridhar et C. Feldmann, ELECTRODIALYSIS IN A NONAQUEOUS MEDIUM - A CLEAN PROCESS FOR THE PRODUCTION OF ACETOACETIC ESTER, Journal of membrane science, 124(2), 1997, pp. 175-179
Citations number
5
Categorie Soggetti
Engineering, Chemical","Polymer Sciences
Journal title
ISSN journal
03767388
Volume
124
Issue
2
Year of publication
1997
Pages
175 - 179
Database
ISI
SICI code
0376-7388(1997)124:2<175:EIANM->2.0.ZU;2-X
Abstract
Alkoxide is used as an agent and consumed in condensation reactions, e .g., in the production of acetoacetic ester. Working in an alcoholic m edium and starting from a salt, it is possible to produce an alkoxide by means of electrodialysis. This principle was applied successfully f or the production of acetoacetic ester and the recovery of the alkoxid e in a single step. Such a process would offer self-sufficiency; the a lkoxide could be recovered, thus foregoing the use of mineral acids an d the consequent production of a salt as a waste. The merits can be se en in an economical as well as in an ecological context.