ELECTRODEPOSITION OF CUINSE2 THIN-FILMS FROM AQUEOUS CITRIC SOLUTIONS.1. INFLUENCE OF POTENTIAL AND MASS-TRANSFER RATE ON COMPOSITION AND STRUCTURE OF FILMS

Authors
MOLIN AN DIKUSAR AI KIOSSE GA PETRENKO PA SOKOLOVSKY AI SALTANOVSKY YG
Citation
An. Molin et al., ELECTRODEPOSITION OF CUINSE2 THIN-FILMS FROM AQUEOUS CITRIC SOLUTIONS.1. INFLUENCE OF POTENTIAL AND MASS-TRANSFER RATE ON COMPOSITION AND STRUCTURE OF FILMS, Thin solid films, 237(1-2), 1994, pp. 66-71
Citations number
8
Categorie Soggetti
Physics, Applied","Material Science","Physics, Condensed Matter
Journal title
Thin solid films → ACNP
ISSN journal
00406090
Volume
237
Issue
1-2
Year of publication
1994
Pages
66 - 71
Database
ISI
SICI code
0040-6090(1994)237:1-2<66:EOCTFA>2.0.ZU;2-4
Abstract
It is shown that by changing, in the negative direction, the potential of citric aqueous solutions containing Cu(II), In(III) and Se(IV) und er cathodic polarization, it is possible to obtain films such as CuSe, Cu3Se2, CuInSe2 and In-enriched CuInSe2. The values of the potentials under which these compounds are formed depends upon the rate of depos ition, the speed of ion mass transfer in the solution, the conductivit y or the electrolyte, the cathode surface area and the electrolyte tem perature.