HOMOCHIRAL MATCHING IN THE DIELS-ALDER CLYCLODIMERIZATION 2-VINYL-7-OXABICYCLO[2.2.1]HEPT-2-ENE DERIVATIVES

Authors
MEERPOEL L VRAHAMI MM ANCEREWICZ J VOGEL P
Citation
L. Meerpoel et al., HOMOCHIRAL MATCHING IN THE DIELS-ALDER CLYCLODIMERIZATION 2-VINYL-7-OXABICYCLO[2.2.1]HEPT-2-ENE DERIVATIVES, Tetrahedron letters, 35(1), 1994, pp. 111-114
Citations number
20
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Tetrahedron letters → ACNP
ISSN journal
00404039
Volume
35
Issue
1
Year of publication
1994
Pages
111 - 114
Database
ISI
SICI code
0040-4039(1994)35:1<111:HMITDC>2.0.ZU;2-L
Abstract
Racemic 6-vinyl-7-oxabicyclo[2.2.1]hept-5-en-2-one, 5-vinyl-7-oxabicyc lo[2.2.1]hept-5-en-2-one and their ethylene acetals undergo highly ste reoselective Diels-Alder cyclodimerizations. The optically pure semicy clic dienes give the corresponding optically pure dimers with the same ease.