PALLADIUM(II) PROMOTED O-GLYCOSYLATION INVOLVING 1-THIO-2-ENOSIDES AND 3-THIO-1-ENOSES

Authors
TAKEDA K NAKAMURA H AYABE A AKIYAMA A HARIGAYA Y MIZUNO Y
Citation
K. Takeda et al., PALLADIUM(II) PROMOTED O-GLYCOSYLATION INVOLVING 1-THIO-2-ENOSIDES AND 3-THIO-1-ENOSES, Tetrahedron letters, 35(1), 1994, pp. 125-128
Citations number
15
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Tetrahedron letters → ACNP
ISSN journal
00404039
Volume
35
Issue
1
Year of publication
1994
Pages
125 - 128
Database
ISI
SICI code
0040-4039(1994)35:1<125:PPOI1A>2.0.ZU;2-5
Abstract
O-glycosylation of thioglycosyl donors, 2,3-dideoxy-hex-1-thio-2-enopy ranosides, 1,2-dideoxy-hex-3-thio-1-nopyranoses ad 2-pyridyl 3,4,6-tet ra-O-benzyl-1-thio-beta-D-glucopyranoside was achieved by use of a Pd( II) activator which was prepared from etonitrile)dichloropalladium(II) (Pd(CH3CN)(2)Cl-2) and silver triflate (AgOTf).