PECULIARITIES OF STRUCTURE AND PROPERTIES OF PHOSPHORUS-CONTAINING CATIONS WITH 2 INTRAMOLECULAR DONOR-ACCEPTOR BONDS N-]P - SYNTHESIS OF THE FIRST 5-COORDINATED P-CATION WITH P=N BOND
Se. Pipko et al., PECULIARITIES OF STRUCTURE AND PROPERTIES OF PHOSPHORUS-CONTAINING CATIONS WITH 2 INTRAMOLECULAR DONOR-ACCEPTOR BONDS N-]P - SYNTHESIS OF THE FIRST 5-COORDINATED P-CATION WITH P=N BOND, Tetrahedron letters, 35(1), 1994, pp. 165-168
cations 1a,b display dual reactivity, and they interact both with elec
trophilic and nucleophilic reagents. Reaction with chloramine B or ben
zenesulphonylazide leads to the formation of first representative of 5
-coordinated P-cations with P=N bond.