CHARACTERIZATION OF TL RARE-GAS COMPLEXES AND COMPARISON WITH OTHER GROUP 3A METAL-COMPLEXES

Authors
STANGASSINGER A SCHEUCHENPFLUG J PRINZ T BONDYBEY VE
Citation
A. Stangassinger et al., CHARACTERIZATION OF TL RARE-GAS COMPLEXES AND COMPARISON WITH OTHER GROUP 3A METAL-COMPLEXES, Chemical physics, 178(1-3), 1993, pp. 533-546
Citations number
46
Categorie Soggetti
Physics, Atomic, Molecular & Chemical
Journal title
Chemical physics → ACNP
ISSN journal
03010104
Volume
178
Issue
1-3
Year of publication
1993
Pages
533 - 546
Database
ISI
SICI code
0301-0104(1993)178:1-3<533:COTRCA>2.0.ZU;2-I
Abstract
The TlAr, TlKr, and TlXe complexes have been produced by sputtering of a Tl electrode, and detected in a supersonic jet expansion by laser e xcitation spectroscopy. Analysis of the B-2 Sigma(+) <-- X(2)II(1/2) a nd B-2 Sigma(t) <-- X(2)II(3/2) transitions yields information about t he vibrational potential and binding energies of the complexes. Their molecular constants are reported and the results are compared with oth er group 3A metals. Comparisons and trends within the group are discus sed.