The structure and orientation of graphite platelets in graphite spheru
lites (GS) in cast irons modified by either cerium or magnesium plus c
erium were investigated by TEM and micro-diffraction. The platelets ha
ve a rhombohedral structure with their [001] directions nearly paralle
l to the radius of the GS, but each platelet is twisted about 2-degree
s over a 1 mum length. Randomly orientated graphite is located in the
interplatelet areas, in which most of the graphite has a hexagonal str
ucture rather than rhombohedral structure. Based on the crystallograph
ic characterization of the graphite and the cerium and magnesium eleme
ntal distribution in the GS, the model for the growth of GS as origina
lly proposed by Double and Hellawell is re-examined.