The chemisorption dynaMiCS Of O2 and Ag(110) was studied by molecular
beams and high resolution electron energy loss spectroscopy by measuri
ng the initial sticking probability S0 as a function of the molecular
translational energy E(i) and angle of incidence theta(i) along [001]
and [110BAR]. S0 scales as E(i)cos(n)theta(i) with n = 1.1 along (001)
and n = 1.6 along [110BAR]. This indicates that parallel momentum has
a role in promoting adsorption. The effect is connected to the amplit
ude of the corrugation seen by the O2 molecule.