SYNTHESIS, STRUCTURE AND PROPERTIES OF CPRU(PPH3)NS2P(OR)2

Citation
Sz. Wu et al., SYNTHESIS, STRUCTURE AND PROPERTIES OF CPRU(PPH3)NS2P(OR)2, Gazzetta chimica italiana, 123(11), 1993, pp. 647-650
Citations number
17
Categorie Soggetti
Chemistry
Journal title
ISSN journal
00165603
Volume
123
Issue
11
Year of publication
1993
Pages
647 - 650
Database
ISI
SICI code
0016-5603(1993)123:11<647:SSAPOC>2.0.ZU;2-7
Abstract
CpRu(PPh3)2Cl (CP = eta5-C5H5, eta5-MeC5H4) react with (RO)2PS2M (M = Na, K, HNEt3; R = Me2CH-, Et-, Ph-, p-MeC6H4-, alpha-naphthyl, o-pheny lene) in MeOH to give new derivatives of ruthenium of the type CpRu(PP h3)nS2P(OR)2 (n = 1 or 2). These compounds were characterized by eleme ntal analysis, NMR and IR spectra.