DISRUPTION OF THE PD(I)-PD(I) DINUCLEAR STRUCTURE BY REACTION OF [PD2(MU-PCY2)(MU-ETA-3-C3H5)(PCY2H)2] WITH BENZENETHIOL - FORMATION AND X-RAY AND NMR CHARACTERIZATION OF TRANS-[PD(SPH)2(PCY2H)2]

Authors
PASQUALI M MARCHETTI F LEONI P BERINGHELLI T DALFONSO G
Citation
M. Pasquali et al., DISRUPTION OF THE PD(I)-PD(I) DINUCLEAR STRUCTURE BY REACTION OF [PD2(MU-PCY2)(MU-ETA-3-C3H5)(PCY2H)2] WITH BENZENETHIOL - FORMATION AND X-RAY AND NMR CHARACTERIZATION OF TRANS-[PD(SPH)2(PCY2H)2], Gazzetta chimica italiana, 123(11), 1993, pp. 659-664
Citations number
25
Categorie Soggetti
Chemistry
Journal title
Gazzetta chimica italiana → ACNP
ISSN journal
00165603
Volume
123
Issue
11
Year of publication
1993
Pages
659 - 664
Database
ISI
SICI code
0016-5603(1993)123:11<659:DOTPDS>2.0.ZU;2-A
Abstract
[Pd2(mu-PCy2)(mu,eta3-C3H5)(PCy2H)2] reacts with an excess of PhSH to yield the mononuclear complex trans-[Pd(SPh)2(PCY2H)2] which was compl etely characterized by solution multinuclear NMR spectroscopy and by a single-crystal X-ray diffraction experiment. Crystal data: for trans- [Pd(SPh)2(PCy2H)2]: triclinic, space group P1BAR, a = 10.061(3), b = 1 3.733(3), c = 14.398(4) angstrom, alpha = 86.46(4), beta = 72.07(2), g amma = 76.57(4)-degrees, U = 1840.9(9) angstrom3, Z = 2, d(calc) = 1.3 01 g cm-1, R = 0.064, R' = 0.050.