Yp. Xue et Hl. Frisch, POLY(2,6-DIMETHYL-L,4-PHENYLENE OXIDE) POLY(BUTADIENE)DIOL INTERPENETRATING POLYMER NETWORKS - PHASE MORPHOLOGICAL-CHARACTERISTICS AND GLASS-TRANSITION TEMPERATURE BEHAVIOR/, Journal of polymer science. Part A, Polymer chemistry, 32(2), 1994, pp. 257-263
The fracture surface topography of simultaneous interpenetrating polym
er networks (SIN'S) of poly(2,6-dimethyl-1,4 phenylene oxide) (PPO)/po
ly(butadiene) diol was examined by scanning electron microscopy (SEM).
The phase morphology of the IPNs is highly dependent on PPO/poly(buta
diene) diol mass ratio. A single-phase morphology of the IPNs was achi
eved when the content of poly(butadiene)diol is below 40 wt % in the i
nitial composition. The SEM observations are also wholly consistent wi
th the glass transition temperature behavior obtained in the different
ial scanning calorimetric (DSC) measurements. (C) 1994 John Wiley & So
ns, Inc.