The operating conditions of a compact, high-neutron-wall-loading fusio
n reactor severely limit the choices for structural, shield, insulator
, and breeder materials. In particular the response of plasma-facing m
aterials to radiation, thermal and pressure stresses, and their compat
ibility with coolants are of primary concern. Material selection issue
s are investigated for the compact, high mass-power-density TITAN-I re
actor design study. In this paper the major findings regarding materia
l performance are discussed. The retention of mechanical strength at r
elatively high temperatures, low thermal stresses, and compatibility w
ith liquid lithium make vanadium-base alloys a promising material for
structural components. Based on limited data, the thermal creep behavi
our of V-3Ti-1Si and V-15Cr-5Ti alloys is approximated using the modif
ied minimum committment method. In addition, the effects of irradiatio
n and helium generation are superimposed on the creep behavior of V-3T
i-1Si. Coolant compatibility issues are investigated. The liquid lithi
um compatibility of the two vanadium alloys, V-15Cr-5Ti and V-3Ti-1Si,
are compared, and the latter was chosen as the primary structural-mat
erial candidate for the liquid-lithium-cooled TITAN-I reactor. Electri
cally insulating materials, capable of operating at high temperatures
are necessary throughout the fusion reactor device. Electrical insulat
or-material issues of concern include irradiation induced swelling and
conductivity. Both issues are investigated and operating temperatures
for minimum swelling and dielectric breakdown strength are identified
for spinel (MgAl2O4).