S. Sharafat et al., MATERIALS SELECTION CRITERIA AND PERFORMANCE ANALYSIS FOR THE TITAN-II REVERSED-FIELD-PINCH FUSION POWER CORE, Fusion engineering and design, 23(2-3), 1993, pp. 201-217
The TITAN-II reactor is a compact, high-neutron-wall-loading (18 MW/m2
) design. The TITAN-II fusion power core (FPC) is cooled by an aqueous
lithium-salt solution that also acts as the breeder material. The use
of an aqueous solution imposes special constraints on the selection o
f structural and breeder material because of corrosion concerns, hydro
gen embrittlement, and radiolytic effects. In this paper, the material
s engineering and design considerations for the TITAN-II FPC are prese
nted. Material selection criteria, based on electrochemical corrosion
mechanisms of aqueous solutions coupled with radiolysis of water by io
nizing radiation, resulted in the choice of a low-activation ferritic
steel as structural material for TITAN-II. Stress corrosion cracking,
hydrogen embrittlement, and changes in the ductile-to-brittle transiti
on temperature of ferritic alloys are discussed. Lithium-nitrate (LiNO
3) salt was chosen over lithium hydroxide (LiOH) because it is less co
rrosive and reduces the net radiolytic decomposition rate of the water
. The dissolved salt in the coolant changes the thermophysical propert
ies of the coolant results in trade-offs between the lithium concentra
tion in the coolant, neutronics performance, thermal and structural de
sign. The TITAN-II design requires a neutron multiplier to achieve an
adequate tritium breeding ratio. Beryllium is the primary neutron mult
iplier, assuming a maximum swelling of about 10% based on continuous s
elf-limiting microcracking/sintering cycles.