Rh. Lacombe et al., COMPARISON OF FINITE-ELEMENT STRESS-ANALYSIS RESULTS WITH PEEL STRENGTH AT THE COPPER-POLYIMIDE INTERFACE, Journal of adhesion science and technology, 7(12), 1993, pp. 1293-1307
An exploratory stress analysis has been performed on dense wiring stru
ctures, such as those used for multichip modules, with the objective o
f anticipating possible delamination failure mechanisms. The structure
consists of an array of parallel copper lines imbedded in a polyimide
insulator, all of which is supported by an underlying silicon wafer.
Different versions include thin layers of silicon nitrides on top of a
nd at the base of the copper lines. Using the finite element technique
, several models were constructed to explore where delamination could
occur in this structure by calculating the driving force (strain energ
y release rate) which could act on any preexisting microcrack or delam
ination. It was found that delaminations propagating from the base of
the copper line up the sidewall were a strong possibility. The predict
ions of the stress analysis were substantiated by transmission electro
n microscopy photographs of real structures which showed the same type
of delamination as that anticipated by stress analysis. For these par
ts, the adhesion between the copper line and the polyimide insulator w
as mediated by a liner of tantalum, which gives weak adhesion to coppe
r under certain circumstances. X-ray photoelectron spectroscopy and pe
er test analyses were used to verify the suspected failure modes.