GRAPHITIC POLYMER STRIPS WITH EDGE STATES

Authors
Citation
Dj. Klein, GRAPHITIC POLYMER STRIPS WITH EDGE STATES, Chemical physics letters, 217(3), 1994, pp. 261-265
Citations number
16
Categorie Soggetti
Physics, Atomic, Molecular & Chemical
Journal title
ISSN journal
00092614
Volume
217
Issue
3
Year of publication
1994
Pages
261 - 265
Database
ISI
SICI code
0009-2614(1994)217:3<261:GPSWES>2.0.ZU;2-3
Abstract
The Huckel band structure is analytically investigated for a family of arbitrary-width pi-network polymers which may be viewed as being cut from the graphite lattice. For wider strips a portion of two nearly no nbonding bands on either side of the Fermi energy are found to be loca lized to opposite edges of the strip. Novel consequences of these edge -localized band orbitals are considered and correlated to a simple res onating valence bond picture.