The influence of the microscopic structure of porous silicon layers on
the dielectric function is determined by spectroscopic ellipsometry.
The investigated layers were formed on high and low p-type doped subst
rates. Their microscopic structure was changed by varying the current
density in the electrochemical formation process. The measured dielect
ric function was found to be extremely sensitive on the microscopic st
ructure. New features occur in the measured dielectric function which
are characteristic for the silicon skeleton in the porous silicon laye
rs.