B. Reinsch et al., THE SOURCE OF FREE IRON IN ZINC-BONDED PERMANENT-MAGNETS BASED ON SM2FE17NX, IEEE transactions on magnetics, 29(6), 1993, pp. 2830-2832
The principal Phase resulting from the reaction of Sm2Fe17 with zinc i
s a solution of Sm in GAMMA-Fe-Zn. At the maximum Sm content this cubi
c phase with a - 0.8984 nm has an approximate composition of (at.%) 5
Sm, 42 Fe, 53 Zn and has no permanent magnetic moment between 4.2 and
600 K. The phase equilibria of the low-Sm alloys in Sm-Fe-Zn show that
isostructural Sm2Fe17 and Sm2Zn17 are not miscible and that. because
of the pervasiveness of equilibria with alpha-Fe. it will be difficult
to eliminate alpha-Fe completely from Zn-bonded magnets.