ADSORPTION OF HALIDE-IONS CL-, BR- AND I- ON THE BASAL FACE OF A CADMIUM SINGLE-CRYSTAL

Authors
NANEVA R DIMITROV N POPOV A VITANOV T BOSTANOV V
Citation
R. Naneva et al., ADSORPTION OF HALIDE-IONS CL-, BR- AND I- ON THE BASAL FACE OF A CADMIUM SINGLE-CRYSTAL, Journal of electroanalytical chemistry [1992], 362(1-2), 1993, pp. 281-286
Citations number
17
Categorie Soggetti
Electrochemistry,"Chemistry Analytical
Journal title
Journal of electroanalytical chemistry [1992]
ISSN journal
15726657 → ACNP
Volume
362
Issue
1-2
Year of publication
1993
Pages
281 - 286
Database
ISI
SICI code
Abstract
A qualitative and quantitative study of the adsorption of halide ions on the electrolytically grown (0001) face of a cadmium single crystal is described. It is found that adsorption increases in the order Cl-<B r-<I-. Comparison with the results for other electrodes shows an incre ase in the adsorption in the sequence Cd(0001)<Cd-poly<Ag(100)<Ag(lll) . An attempt is made to explain this sequence in terms of the hydrophi licity of the electrode investigated.