Mb. Rao et S. Sircar, NANOPOROUS CARBON MEMBRANES FOR SEPARATION OF GAS-MIXTURES BY SELECTIVE SURFACE FLOW, Journal of membrane science, 85(3), 1993, pp. 253-264
A novel nanoporous carbon membrane produced by carbonization of poly(v
inylidene chloride) is described. The membrane separates gas mixtures
by selective adsorption and surface diffusion of the more strongly ads
orbed components. In particular, the membrane can very efficiently sep
arate hydrocarbons from hydrogen from low-pressure gas streams. The me
thod of preparation of the membrane and its characterization, pure and
mixed gas permeabilities through the membrane, as well as an industri
al application are reported.