AMINOALANE DIMERS AND TRIMERS - AN EXAMINATION OF STRUCTURAL AND STERIC TRENDS

Authors
SCHAUER SJ ROBINSON GH
Citation
Sj. Schauer et Gh. Robinson, AMINOALANE DIMERS AND TRIMERS - AN EXAMINATION OF STRUCTURAL AND STERIC TRENDS, Journal of coordination chemistry, 30(3-4), 1993, pp. 197-214
Citations number
47
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Journal of coordination chemistry → ACNP
ISSN journal
00958972
Volume
30
Issue
3-4
Year of publication
1993
Pages
197 - 214
Database
ISI
SICI code
0095-8972(1993)30:3-4<197:ADAT-A>2.0.ZU;2-C
Abstract
Reaction of aluminum alkyls with primary or secondary amines readily a ffords dimeric or trimeric aminoalanes. Steric constraints of the subs tituents on aluminum and nitrogen substantially affect the structural nature of the products. Ring size, conformational data, and structural trends are reported for a number of dimeric and trimeric aminoalanes.