CRYSTAL-STRUCTURE OF LOROTRIPHENYLTIN-CENTER-DOT-DIPHENYLCYCLOPROPENONE

Authors
NG SW DAS VGK
Citation
Sw. Ng et Vgk. Das, CRYSTAL-STRUCTURE OF LOROTRIPHENYLTIN-CENTER-DOT-DIPHENYLCYCLOPROPENONE, Journal of crystallographic and spectroscopic research, 23(12), 1993, pp. 929-932
Citations number
11
Categorie Soggetti
Crystallography,Spectroscopy
Journal title
Journal of crystallographic and spectroscopic research → ACNP
ISSN journal
02778068
Volume
23
Issue
12
Year of publication
1993
Pages
929 - 932
Database
ISI
SICI code
0277-8068(1993)23:12<929:COL>2.0.ZU;2-W
Abstract
Triphenyltin chloride forms with diphenyrcyclopropenone a 1/1 molecula r complex belonging to the triclinic P ($) over bar 1 space group (a=1 0.267(4), b=12.095(2), c=12.319(3)Angstrom, alpha=90.67(2), beta=101.5 9(2), gamma=112.58(2)degrees). The tin atom exists in a distorted tran s-trigonal bipyramidal (Sn-C=2.112(3), 2.123(3), 2.137(4), Sn-Cl=2.440 (1), Sn-O=2.510(2)Angstrom) geometry, being displaced out of the equat orial plane (Sigma C-Sn-C=354.3(3)degrees) towards the apical chlorine atom by 0.269(1)Angstrom.