DIACETYLENE-CONTAINING POLYMERS .3. POLY(M,M'-BUTADIYNYLENESUCCINDIANILIDE) AND POLY(M,M'-BUTADIYNYLENE SEBACODIANILIDE) - NOVEL MATERIALS FOR PREPARATION OF TRANSPARENT POLYDIACETYLENE CONTAINING FILMS

Authors
FOMINE S OGAWA T
Citation
S. Fomine et T. Ogawa, DIACETYLENE-CONTAINING POLYMERS .3. POLY(M,M'-BUTADIYNYLENESUCCINDIANILIDE) AND POLY(M,M'-BUTADIYNYLENE SEBACODIANILIDE) - NOVEL MATERIALS FOR PREPARATION OF TRANSPARENT POLYDIACETYLENE CONTAINING FILMS, Polymer Journal, 26(1), 1994, pp. 93-97
Citations number
12
Categorie Soggetti
Polymer Sciences
Journal title
Polymer Journal → ACNP
ISSN journal
00323896
Volume
26
Issue
1
Year of publication
1994
Pages
93 - 97
Database
ISI
SICI code
0032-3896(1994)26:1<93:DP.P>2.0.ZU;2-#
Abstract
New bis-acetylenic monomers; succin(m-ethynyl)dianilide and sebaco(m-e thynyl)dianilide were synthesized and polymerized by oxidative polycou pling to give high molecular weight semicrystalline polymers. These po lymers were found to be highly light sensitive and turned blue on UV-i rradiation to give transparent blue films with absorption maximum beyo nd 600 nm. The polymers were found to be rather stable on heating and thermal cross-linking via diacetylene groups took place only above 170 -degrees-C.