INFRARED MULTIPHOTON DECOMPOSITION OF HIGHLY EXCITED T-BUTYL CHLORIDE-D(9)

Authors
MCALPINE RD MCRAE GA GOODALE JW
Citation
Rd. Mcalpine et al., INFRARED MULTIPHOTON DECOMPOSITION OF HIGHLY EXCITED T-BUTYL CHLORIDE-D(9), International journal of chemical kinetics, 26(2), 1994, pp. 247-257
Citations number
20
Categorie Soggetti
Chemistry Physical
Journal title
International journal of chemical kinetics → ACNP
ISSN journal
05388066
Volume
26
Issue
2
Year of publication
1994
Pages
247 - 257
Database
ISI
SICI code
0538-8066(1994)26:2<247:IMDOHE>2.0.ZU;2-X
Abstract
The infrared multiphoton decomposition (IR MPD) of t-butyl chloride-d9 as a function of pressure and fluence is reported. The major decompos ition route was molecular elimination of DCl in accord with earlier py rolysis studies. The effect of added gases (2-methyl propene-d8, DCl a nd 2-methyl propene-h8) on the MPD is presented. This study is a furth er example of the utility of a new method of analysis of MPD experimen ts. (C) 1994 John Wiley & Sons, Inc.