SALT EFFECTS UPON REACTIONS OF DIFFERENT CHARGE TYPE REACTANTS - PEROXODISULFATE OXIDATIONS OF FE(CN)4(BPY)2-, CIS-FE(CN)2(BPY)2 AND FE(BPY)3(2+) AND IRON(II) OXIDATION BY CO(NH3)5CL2+

Authors
MUNOZ E GRACIANI MD JIMENEZ R RODRIGUEZ A MOYA ML SANCHEZ F
Citation
E. Munoz et al., SALT EFFECTS UPON REACTIONS OF DIFFERENT CHARGE TYPE REACTANTS - PEROXODISULFATE OXIDATIONS OF FE(CN)4(BPY)2-, CIS-FE(CN)2(BPY)2 AND FE(BPY)3(2+) AND IRON(II) OXIDATION BY CO(NH3)5CL2+, International journal of chemical kinetics, 26(2), 1994, pp. 299-307
Citations number
22
Categorie Soggetti
Chemistry Physical
Journal title
International journal of chemical kinetics → ACNP
ISSN journal
05388066
Volume
26
Issue
2
Year of publication
1994
Pages
299 - 307
Database
ISI
SICI code
0538-8066(1994)26:2<299:SEUROD>2.0.ZU;2-0
Abstract
Salt effects on the oxidation of the iron(II) complexes Fe(CN)4(bpy)2- , cis-(CN)2(bpy)2 and Fe(bpy)3(2+) by S2O82- as well as on the reactio n Fe2+ + Co(NH3)5Cl2+ have been studied in concentrated electrolyte so lutions at 298.2 K. We have gone from anion-anion to cation-cation rea ction with the intermediate cases of anion-neutral and cation - anion reactions. Results show that the main cause of the kinetic salt effect s observed is the interaction between supporting electrolytes and the solvent. (C) 1994 John Wiley & Sons, Inc.