V. Dusek et al., DETERMINATION OF DIFFUSION-COEFFICIENTS OF GASES THROUGH A FLAT POLYMERIC MEMBRANE BY THE METHOD OF NONLINEAR-REGRESSION, Collection of Czechoslovak Chemical Communications, 58(12), 1993, pp. 2836-2845
Non-linear regression was applied for calculation of diffusion coeffic
ients of gases through a flat polymeric membrane from the experimental
data obtained by the flow permeation method with the thermal conducti
vity detection of composition of gaseous mixture. To verify this metho
d a polyethylene and carbon dioxide was chosen. Diffusion coefficients
of carbon dioxide in the low-density polyethylene of two different th
ickness at the temperature of 25-degrees-C were determined with precis
ion about +/- 2.5% in agreement with literature.