We studied the electric field effect on spectral holes burned in the S
,cSo absorption band of in poly(vinyl butyral) film doped chlorophyll
(Chl) a at a temperature of T = 2.0 K. With the laser light beam colli
nearly applied, the external electric field produced a symmetric broad
ening of the holes which showed a linear dependence on the field stren
gth. This effect was ascribed to the matrix-induced dipole moment diff
erence (Delta mu(ind)) between the S-1 and S-0 states of Chl a. The re
latively small value of Delta mu(ind) (0.217 D), is in accord with the
change of the molecular polarizability upon electronic excitation. Th
e low-temperature permanent dipole moment difference of Chl a was esti
mated to be less than 0.1 D.