A PHOTON-ECHO STUDY OF PENTACENE IN NAPHTHALENE AT HIGH-PRESSURE

Citation
Ra. Crowell et El. Chronister, A PHOTON-ECHO STUDY OF PENTACENE IN NAPHTHALENE AT HIGH-PRESSURE, Chemical physics letters, 216(3-6), 1993, pp. 293-299
Citations number
33
Categorie Soggetti
Physics, Atomic, Molecular & Chemical
Journal title
ISSN journal
00092614
Volume
216
Issue
3-6
Year of publication
1993
Pages
293 - 299
Database
ISI
SICI code
0009-2614(1993)216:3-6<293:APSOPI>2.0.ZU;2-3
Abstract
Temperature-dependent (2-10 K) photon echo measurements are presented for pentacene in naphthalene at high pressure (12.5 kbar) in a diamond anvil cell. A decrease in the homogeneous dephasing rate (i.e. a narr owing of the homogeneous linewidth) is observed at high pressure. In a ddition, the temperature dependence of the homogeneous dephasing rate is used to obtain the effect of pressure on the frequency and lifetime of the pseudolocal phonon associated with a pentacene impurity in a c rystalline naphthalene matrix.